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PGPR (polyglycerol polyricinoleate)

PGPR (polyglycerol polyricinoleate) suppliers and sourcing guide

PGPR (polyglycerol polyricinoleate) is a lipophilic emulsifier made by esterifying polyglycerol with condensed castor oil fatty acids, which are mostly ricinoleic acid. It is a viscous, yellowish liquid. Chocolate and compound coating makers use it at low levels, often with lecithin, to lower the yield value of molten chocolate, and it is also used in water-in-oil spreads.

Also known as
PGPR · Polyglycerol polyricinoleate · E476 · Polyglycerol esters of interesterified ricinoleic acid
Facts checked
November 2026

Forms and grades of PGPR (polyglycerol polyricinoleate)

Suppliers sell different products under the same name. Specify the one you need.

  • Standard liquid

    The usual form, a clear to slightly cloudy viscous liquid supplied in drums or IBCs.

  • Blends with lecithin

    Premixed PGPR and lecithin systems for chocolate viscosity control.

  • Kosher and halal grades

    Grades certified for kosher or halal use, since castor oil and glycerol sources must be documented.

What to check on the COA

Compare each result with your own specification when the lot arrives.

Acid value
Free acid by titration, which rises if the ester hydrolyzes.
Hydroxyl value and saponification value
Titration results that characterize the ester against the supplier's or FCC specification.
Refractive index and viscosity
Physical identity checks that also flag off-spec batches.
Polyglycerol composition
Distribution of di-, tri- and tetraglycerol and limits on higher polyglycerols, reported per the supplier's specification.
Heavy metals
Lead, and often arsenic, cadmium and mercury, by ICP-MS or AAS against the supplier's specification or Food Chemicals Codex (FCC) limits.

Storage, lots and expiry

Storage and shelf life

Store PGPR in closed drums or IBCs at moderate temperature, away from direct heat and light, and keep containers sealed to limit oxidation and moisture pickup. It becomes thick when cold, so warm gently before pumping if needed. Shelf life is set by the supplier's specification, usually with a retest of acid value for older stock.

Lots and expiry dates

Viscosity and acid value can differ between lots and affect how much is needed to reach a target chocolate viscosity. Record both from each COA and verify chocolate rheology when switching lots or suppliers.

Regulatory status

Facts from regulators and standards bodies, each linked to its source.

  • GRN 266 (polyglycerol polyricinoleate, notified by Palsgaard A/S) closed on May 29, 2009 with FDA having no questions, for use as an emulsifier in chocolate-type products based on vegetable fats other than cocoa butter.

    Source: hfpappexternal.fda.gov (opens in a new tab)

This is general information, not regulatory advice. Status differs by country and by how the ingredient is used, so check the rules for your product and market.

PGPR (polyglycerol polyricinoleate) suppliers

Manufacturers and distributors whose own websites say they sell it.

  • Palsgaard

    Manufacturer · Juelsminde, Denmark

    Danish emulsifier and stabiliser maker supplying PGPR, ammonium phosphatide and polyglycerol ester and monoglyceride emulsifiers to chocolate, bakery, dairy, margarine and ice cream producers.

    • ISO 9001
    • FSSC 22000
    • Kosher
    • Halal

Suppliers are in alphabetical order and none pays to appear. Each claim is checked against the supplier’s own website on the date shown. Ask for the specification sheet and a recent COA before you order, and confirm details with the supplier.

Frequently asked questions

What forms of PGPR (polyglycerol polyricinoleate) can brands buy?

Common forms include standard liquid, blends with lecithin and kosher and halal grades. Ask each supplier for the specification sheet of the exact grade they quote.

What should the COA for PGPR (polyglycerol polyricinoleate) include?

Expect acid value, hydroxyl value and saponification value, refractive index and viscosity, polyglycerol composition and heavy metals, each with its method, specification and result for that lot.

How should PGPR (polyglycerol polyricinoleate) be stored?

Store PGPR in closed drums or IBCs at moderate temperature, away from direct heat and light, and keep containers sealed to limit oxidation and moisture pickup. It becomes thick when cold, so warm gently before pumping if needed. Shelf life is set by the supplier's specification, usually with a retest of acid value for older stock.

What is the regulatory status of PGPR (polyglycerol polyricinoleate)?

GRN 266 (polyglycerol polyricinoleate, notified by Palsgaard A/S) closed on May 29, 2009 with FDA having no questions, for use as an emulsifier in chocolate-type products based on vegetable fats other than cocoa butter.

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