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Monocalcium phosphate

Monocalcium phosphate suppliers and sourcing guide

Monocalcium phosphate (MCP) is a fast-acting leavening acid that reacts with sodium bicarbonate as soon as a batter or dough is mixed. It is used in baking powder, self-rising flour, pancake and biscuit mixes, and as a calcium and phosphorus source in fortified foods. It is made by reacting phosphoric acid with lime or calcium carbonate and drying the product. Brands buy it as the monohydrate or as coated anhydrous MCP, which reacts more slowly.

Also known as
MCP · Calcium phosphate monobasic · Calcium dihydrogen phosphate · E341(i)
Facts checked
November 2026

Forms and grades of monocalcium phosphate

Suppliers sell different products under the same name. Specify the one you need.

  • Monohydrate

    MCP·H2O, the standard fast-acting form for baking powder and mixes.

  • Coated anhydrous

    Anhydrous MCP with a coating that slows its first reaction, used in prepared mixes and self-rising flour.

  • Nutritional grade

    MCP used as a calcium and phosphorus source, specified by calcium and phosphorus content.

  • Organic-compliant

    Grades used in organic products under the calcium phosphates listing.

What to check on the COA

Compare each result with your own specification when the lot arrives.

Assay
Calcium and phosphorus content by complexometric titration or ICP, per FCC.
Neutralizing value
Parts of sodium bicarbonate neutralized by 100 parts of MCP, used to balance leavening.
Loss on ignition
Separates monohydrate from anhydrous grades and flags moisture pickup.
Fluoride
Fluoride by ion-selective electrode against FCC limits.
Lead and arsenic
Trace elements by ICP-MS.
Particle size
Sieve analysis, which affects reaction speed and blending.

Storage, lots and expiry

Storage and shelf life

Store sealed in a cool, dry area; moisture causes caking and early reaction. Keep it apart from bicarbonate until blending. Shelf life follows the supplier specification, with a retest of neutralizing value and moisture for older stock.

Lots and expiry dates

Record grade (monohydrate or coated anhydrous) and neutralizing value for each lot, and recheck leavening balance when either changes. Rotate stock FEFO.

Regulatory status

Facts from regulators and standards bodies, each linked to its source.

This is general information, not regulatory advice. Status differs by country and by how the ingredient is used, so check the rules for your product and market.

Monocalcium phosphate suppliers

Manufacturers and distributors whose own websites say they sell it.

  • Innophos

    Manufacturer · Cranbury, NJ

    US manufacturer of food, pharmaceutical and technical grade phosphates, including phosphoric acid, sodium and calcium phosphates, leavening acids and polyphosphates.

Suppliers are in alphabetical order and none pays to appear. Each claim is checked against the supplier’s own website on the date shown. Ask for the specification sheet and a recent COA before you order, and confirm details with the supplier.

Frequently asked questions

What forms of monocalcium phosphate can brands buy?

Common forms include monohydrate, coated anhydrous, nutritional grade and organic-compliant. Ask each supplier for the specification sheet of the exact grade they quote.

What should the COA for monocalcium phosphate include?

Expect assay, neutralizing value, loss on ignition, fluoride, lead and arsenic and particle size, each with its method, specification and result for that lot.

How should monocalcium phosphate be stored?

Store sealed in a cool, dry area; moisture causes caking and early reaction. Keep it apart from bicarbonate until blending. Shelf life follows the supplier specification, with a retest of neutralizing value and moisture for older stock.

What is the regulatory status of monocalcium phosphate?

21 CFR 182.6215 lists monobasic calcium phosphate as GRAS when used in accordance with good manufacturing practice. 7 CFR 205.605(b) allows calcium phosphates (monobasic, dibasic and tribasic) as synthetic substances in organic products. Health Canada's List of Permitted pH Adjusting Agents, Acid-Reacting Materials and Water Correcting Agents includes monobasic calcium phosphate as an acid-reacting material in baking powder.

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